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From: "Michael A. Kangin" <mak@complife.ru>
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Date: Tue, 6 Sep 2016 15:48:42 +0200
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On 09/06/2016 11:21 AM, Vladimir Karpinsky wrote:

>  status=bounced (host a.b.c[xxx.xxx1xxx.xxx] said: 530 5.7.0 Must issue
> a STARTTLS command first (in reply to MAIL FROM command и т.д.
>
> Откуда взялось это требование про использование STARTTLS и как бы его
> отключить обратно?

Может у вас раньше SSL втихую использовалась, а потом новая libssl 
приехала и старые протоколы поломала?